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9 - N u m e r i c a l   1 0

Problem

An electron is in the first Bohr orbit of hydrogen. Find:
(a) The speed of the electron.
(b) The time required for the electron to circle the nucleus.

Data

  • Energy level (nn): 11
  • Planck’s constant (hh): 6.626×10−34 Js6.626 \times 10^{-34} \, \mathrm{Js}
  • Mass of the electron (mm): 9.109×10−31 kg9.109 \times 10^{-31} \, \mathrm{kg}
  • Radius of the first Bohr orbit (r1r_1): 0.53×10−10 m0.53 \times 10^{-10} \, \mathrm{m}
  • Ï€\pi: 3.143.14

To Find:

  1. Speed of the electron (vv)
  2. Time period (TT)

Prerequisite Concepts

  1. Bohr’s Second Postulate:
    The angular momentum of the electron is quantized:
mvrn=nh2Ï€ m v r_n = n \frac{h}{2 \pi}

Solving for vv:

v=nh2Ï€mr1 v = n \frac{h}{2 \pi m r_1}
  1. Time Period (TT):
    The time required for the electron to circle the nucleus is:
T=Circumference of the orbitSpeed of the electron T = \frac{\text{Circumference of the orbit}}{\text{Speed of the electron}}

Substituting:

T=2Ï€r1v T = \frac{2 \pi r_1}{v}

Solution

Part (a): Speed of the Electron (vv)

Using Bohr’s second postulate:

v=nh2Ï€mr1v = n \frac{h}{2 \pi m r_1}

Substitute n=1n = 1, h=6.626×10−34 Jsh = 6.626 \times 10^{-34} \, \mathrm{Js}, m=9.109×10−31 kgm = 9.109 \times 10^{-31} \, \mathrm{kg}, and r1=0.53×10−10 mr_1 = 0.53 \times 10^{-10} \, \mathrm{m}:

v=6.626×10−342⋅3.14⋅9.109×10−31⋅0.53×10−10v = \frac{6.626 \times 10^{-34}}{2 \cdot 3.14 \cdot 9.109 \times 10^{-31} \cdot 0.53 \times 10^{-10}}

Simplify:

v=6.626×10−343.038×10−30v = \frac{6.626 \times 10^{-34}}{3.038 \times 10^{-30}} v=2.19×106 m/sv = 2.19 \times 10^{6} \, \mathrm{m/s}

Part (b): Time Period (TT)

Using the formula for time period:

T=2Ï€r1vT = \frac{2 \pi r_1}{v}

Substitute r1=0.53×10−10 mr_1 = 0.53 \times 10^{-10} \, \mathrm{m} and v=2.19×106 m/sv = 2.19 \times 10^{6} \, \mathrm{m/s}:

T=2⋅3.14⋅0.53×10−102.19×106T = \frac{2 \cdot 3.14 \cdot 0.53 \times 10^{-10}}{2.19 \times 10^{6}}

Simplify:

T=3.3284×10−102.19×106T = \frac{3.3284 \times 10^{-10}}{2.19 \times 10^{6}} T=1.52×10−16 sT = 1.52 \times 10^{-16} \, \mathrm{s}

Answer

  1. Speed of the electron:
v=2.19×106 m/s v = 2.19 \times 10^{6} \, \mathrm{m/s}
  1. Time period:
T=1.52×10−16 s T = 1.52 \times 10^{-16} \, \mathrm{s}